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What are acids and bases, and how do they react to form salts?

Acids, bases and alkalis in terms of hydrogen and hydroxide ions, the pH scale and indicators, neutralisation, and the reactions of acids with metals, oxides, hydroxides and carbonates.

A CCEA GCSE Chemistry answer on acids, bases and salts, covering acids and alkalis in terms of hydrogen and hydroxide ions, the pH scale and indicators, neutralisation, and the four reactions of acids with metals, metal oxides, hydroxides and carbonates.

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  1. What this dot point is asking
  2. Acids, bases and alkalis
  3. The pH scale and indicators
  4. Neutralisation
  5. The four reactions of acids
  6. Worked example
  7. Examples in context
  8. Strong and weak, concentrated and dilute
  9. Try this

What this dot point is asking

CCEA wants you to define acids, bases and alkalis using hydrogen and hydroxide ions, use the pH scale and indicators, explain neutralisation, and give the products of acids reacting with metals, metal oxides, metal hydroxides and carbonates.

Acids, bases and alkalis

Common acids are hydrochloric, sulfuric and nitric acid. Common alkalis are sodium hydroxide and potassium hydroxide. Metal oxides and carbonates are bases that may be insoluble.

The pH scale and indicators

Indicators show pH by colour. Universal indicator gives a range of colours (red for strong acid through green at neutral to purple for strong alkali). Litmus turns red in acid and blue in alkali. A pH meter gives a precise numerical value.

Neutralisation

The salt formed depends on the acid: hydrochloric acid gives chlorides, sulfuric acid gives sulfates, and nitric acid gives nitrates. The metal part comes from the base.

The four reactions of acids

Each can be tested in the lab: the metal reaction fizzes and gives a gas that pops with a lit splint; the carbonate reaction fizzes and the gas turns limewater milky.

Worked example

Examples in context

Example 1. Treating indigestion
Antacid tablets contain bases such as magnesium hydroxide or calcium carbonate that neutralise excess stomach acid (hydrochloric acid), forming a salt and water (and carbon dioxide from carbonates). This is neutralisation put to medical use.
Example 2. Correcting acidic soil
Farmers add lime (calcium oxide or carbonate, both bases) to neutralise acidic soil and raise its pH so crops grow better. The reaction of a base with the acid in the soil is exactly the neutralisation studied here.
Example 3. Why fizzing reveals a carbonate
Pouring dilute acid on an unknown white powder and seeing it fizz, with the gas turning limewater milky, is a quick way to show the powder is a carbonate. Builders use this to tell limestone (calcium carbonate) from other pale rocks, a direct field use of the acid-carbonate reaction.

Strong and weak, concentrated and dilute

Two pairs of words are easy to confuse. Strong and weak describe how fully an acid splits into ions in water: a strong acid (hydrochloric, sulfuric, nitric) ionises completely, while a weak acid (such as ethanoic acid in vinegar) only partly ionises. Concentrated and dilute describe how much acid is dissolved per volume of water. So a dilute solution of a strong acid is possible, and so is a concentrated solution of a weak acid. CCEA expects you to keep these ideas separate, because they explain why two acids at the same concentration can have different pH values.

Try this

Q1. State the pH of a neutral solution. [1 mark]

  • Cue. pH 7.

Q2. Name the products when hydrochloric acid reacts with zinc. [2 marks]

  • Cue. Zinc chloride and hydrogen.

Exam-style practice questions

Practice questions written in the style of CCEA exam questions on this dot point, with worked answer explainers. The year tag is the paper they imitate, not the source.

CCEA 20184 marksHydrochloric acid reacts with magnesium and, separately, with copper(II) oxide. Write a word equation for each reaction and name the type of reaction in each case.
Show worked answer β†’

Markers want the correct products for each acid reaction.

Acid plus metal gives a salt plus hydrogen:
hydrochloric acid + magnesium gives magnesium chloride + hydrogen. This is a displacement/redox reaction (the metal displaces hydrogen).

Acid plus metal oxide gives a salt plus water:
hydrochloric acid + copper(II) oxide gives copper(II) chloride + water. This is a neutralisation reaction (the metal oxide is a base).

Markers reward both word equations with the correct salt (a chloride from hydrochloric acid), hydrogen from the metal reaction, water from the oxide reaction, and naming neutralisation for the oxide.

CCEA 20213 marksExplain what is meant by neutralisation, give the ionic equation, and state the pH of a neutral solution.
Show worked answer β†’

The marks are for the definition, the ionic equation and the pH.

Neutralisation is the reaction of an acid with a base (or alkali) to form a salt and water. The hydrogen ions from the acid react with the hydroxide ions from the alkali.

The ionic equation is:

H+(aq)+OHβˆ’(aq)β†’H2O(l)\text{H}^+(aq) + \text{OH}^-(aq) \rightarrow \text{H}_2\text{O}(l)

A neutral solution has a pH of 7.

Markers reward acid plus base gives salt plus water, the H+ plus OH- ionic equation, and pH 7.

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