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WalesChemistryQuick questions

Unit 1: The Language of Chemistry, Structure and Physical Chemistry

Quick questions on Basic ideas about atoms - WJEC A-Level Chemistry

6short Q&A pairs drawn directly from our worked dot-point answer. For full context and worked exam questions, read the parent dot-point page.

What are electron configurations?
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Electrons occupy sub-shells in order of increasing energy: 1s,2s,2p,3s,3p,4s,3d,4p1s, 2s, 2p, 3s, 3p, 4s, 3d, 4p. The 4s4s sub-shell fills before 3d3d because it is slightly lower in energy.
What are successive ionisation energies?
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The first ionisation energy is the energy to remove one mole of electrons from one mole of gaseous atoms: X(g)X(g)++e\text{X}_{(g)} \rightarrow \text{X}^+_{(g)} + e^-. Successive ionisation energies always rise because each electron is pulled from an increasingly positive ion. A large jump appears when the next electron comes from a shell closer to the nucleus, which reveals how many electrons are in each shell, and so which group the element is in.
What are mass spectrometry in dating and forensics?
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TOF mass spectrometers identify trace isotopes in archaeology (carbon dating) and detect doping agents in sport, applying exactly the abundance-to-mass-spectrum logic above. Ionisation energy and the periodic table. The pattern of successive ionisation energies for sodium (one easy electron, then a huge jump) was historical evidence that placed it in Group 1, confirming the shell model that underpins the modern periodic table.
What is q1?
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Write the full electron configuration of an iron atom. [1 mark]
What is q2?
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A sample of boron is 20.0 percent boron-10 and 80.0 percent boron-11. Calculate its relative atomic mass. [2 marks]
What is q3?
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Outline the four stages by which a time-of-flight mass spectrometer separates ions. [4 marks]

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