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WalesChemistryQuick questions

Unit 3: Physical and Inorganic Chemistry

Quick questions on Chemistry of the p-block - WJEC A-Level Chemistry

7short Q&A pairs drawn directly from our worked dot-point answer. For full context and worked exam questions, read the parent dot-point page.

What are period 3 chlorides?
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The chlorides change character across the period in step with the bonding. Sodium and magnesium chlorides are ionic solids that dissolve to give roughly neutral solutions. Aluminium chloride is covalent (it sublimes and exists as Al2Cl6\text{Al}_2\text{Cl}_6 dimers) and hydrolyses in water to give an acidic solution. Silicon tetrachloride and phosphorus chlorides are simple covalent molecules that hydrolyse vigorously, fuming in moist air as they release hydrogen chloride: SiCl4+2H2OSiO2+4HCl\text{SiCl}_4 + 2\text{H}_2\text{O} \rightarrow \text{SiO}_2 + 4\text{HCl}.
What is lead in pigments and stability?
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The inert pair effect explains why lead's stable ion is Pb2+\text{Pb}^{2+}, underlying lead(II) compounds used historically in paints and glazes. Halide tests in analysis. The silver nitrate then ammonia sequence is the standard qualitative test for chloride, bromide and iodide in water and unknown salts.
What is q1?
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Classify aluminium oxide as acidic, basic or amphoteric. [1 mark]
What is q2?
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State the colour of the precipitate when silver nitrate is added to aqueous sodium iodide. [1 mark]
What is q3?
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State why the silver(I) ion test for halides is carried out in acidic conditions. [1 mark]
What is q4?
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Write the equation for the hydrolysis of silicon tetrachloride. [1 mark]
What is q5?
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State the test result for ammonium ions with warm sodium hydroxide. [1 mark]

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