How do we represent chemical reactions with equations, and why is mass always conserved?
Word and balanced symbol equations, conservation of mass, balancing equations, ionic equations, and explaining apparent mass changes in open systems.
A focused answer to OCR Gateway GCSE Chemistry A topic C3.1 on chemical equations and conservation of mass, covering word and balanced symbol equations, how to balance equations, ionic equations, and explaining apparent changes in mass in open systems.
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What this dot point is asking
OCR wants you to write word and balanced symbol equations, apply the law of conservation of mass, balance equations correctly, write simple ionic equations, and explain why mass can appear to change in an open container even though it is always conserved overall. Equations and conservation of mass run through the whole of chemistry.
Word and symbol equations
For example, the word equation magnesium + oxygen produces magnesium oxide becomes the symbol equation . The arrow means "reacts to form". State symbols (, , , ) can be added to show the physical states.
Conservation of mass
Balancing equations
To balance a symbol equation:
- Write the correct formulae for all reactants and products (do not change these).
- Count the atoms of each element on both sides.
- Add balancing numbers in front of formulae to make each element equal.
- Recount to check every element balances.
The golden rule is that you may only change the big numbers in front of formulae, never the small subscript numbers inside a formula, because changing a subscript changes the substance.
Ionic equations
Apparent changes in mass
Although mass is always conserved, it can appear to change in an open container:
- If a reaction gives off a gas (for example a carbonate releasing carbon dioxide), the gas escapes into the air, so the mass of what is left appears to decrease. The total mass, including the gas, is unchanged.
- If a reaction takes in a gas (for example a metal reacting with oxygen from the air), the gas joins the solid, so the mass appears to increase.
In a sealed container, no gas can enter or leave, so the measured mass stays constant.
Exam-style practice questions
Practice questions written in the style of OCR exam questions on this dot point, with worked answer explainers. The year tag is the paper they imitate, not the source.
OCR 20183 marksBalance the symbol equation for the combustion of methane: . Show the balanced equation.Show worked answer β
A C3.1 balancing question. Reward: start with . The carbon balances (1 each). There are 4 hydrogens on the left, so put a before water to give 4 hydrogens: . Now count oxygen on the right: 2 (in ) plus 2 (in ) = 4, so put a before on the left to give 4 oxygens. The balanced equation is . Markers credit balancing hydrogen with the 2 before water and oxygen with the 2 before , giving the fully balanced equation. A common slip is changing a formula instead of adding a balancing number.
OCR 20214 marksA student burns a piece of magnesium in air in an open crucible and finds the mass increases. In a separate sealed flask, a reaction between two solutions shows no change in mass. Explain both observations using conservation of mass.Show worked answer β
A Higher tier application question. Reward: in every chemical reaction, atoms are rearranged but not created or destroyed, so mass is always conserved overall. When magnesium burns in the open crucible, it reacts with oxygen from the air to form magnesium oxide; the oxygen adds to the magnesium, so the mass of the solid increases (the extra mass comes from the oxygen that has joined). In the sealed flask, no substances can enter or leave, so the total mass stays the same: the products have exactly the same mass as the reactants. Markers credit conservation of mass (atoms rearranged, not lost or made), the magnesium gaining mass from oxygen in the air, and the sealed flask keeping all atoms inside so the mass is unchanged.
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