How do we calculate the mass of a product from the mass of a reactant?
Reacting masses; using moles to calculate the mass of a product or reactant; limiting reactants; and deducing balanced equations from masses.
A focused answer to AQA GCSE Chemistry 4.3.2 and 4.3.3, covering how to calculate reacting masses using moles and mole ratios, the idea of a limiting reactant, and using masses to deduce the balancing numbers in an equation.
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What this dot point is asking
AQA wants you to calculate the mass of a product or reactant using moles and the mole ratio from a balanced equation, identify and use the limiting reactant, and deduce the balancing numbers of an equation from reacting masses. This is the workhorse calculation of the topic and appears on almost every Paper 1. The limiting reactant and equation-deduction work is Higher tier.
Calculating reacting masses
Follow the three-step method, which works for any equation:
- Convert the known mass to moles: .
- Use the mole ratio from the balanced equation.
- Convert the result back to mass: .
The same three steps work whether you measure in grams, kilograms or tonnes, because the mole ratio is a pure number. Industrial calculations (extracting iron, making ammonia) are usually set in tonnes but solved identically.
Limiting reactants (Higher)
Adding more of the limiting reactant makes more product; adding more of the reactant in excess makes no difference to the amount of product. To find the limiting reactant, work out the moles of each reactant and compare them with the mole ratio in the equation. The reactant that provides fewer moles relative to the ratio is limiting, which is not always the one with the smaller mass.
Deducing balancing numbers (Higher)
If you know the masses that react, convert each to moles and find the simplest whole-number ratio of moles. This ratio gives the balancing numbers in the equation. For example, if g of sodium (, so mol) reacts with g of oxygen (, so mol), the Na to ratio is , giving .
Try this
Q1. For , calculate the mass of made from g of carbon ( C = 12, CO2 = 44). [3 marks]
- Cue. Moles C ; ratio ; mass CO2 g.
Q2. Define the limiting reactant. [1 mark]
- Cue. The reactant that is used up first and so controls the amount of product.
Q3. g of iron () reacts completely with sulfur to make iron sulfide, . Calculate the mass of sulfur that reacts ( S = 32). [3 marks]
- Cue. Moles Fe ; ratio Fe to S is , so mol of S; mass g.
Exam-style practice questions
Practice questions written in the style of AQA exam questions on this dot point, with worked answer explainers. The year tag is the paper they imitate, not the source.
AQA 20194 marksIron is extracted in the blast furnace by the reaction . Calculate the maximum mass of iron that can be extracted from tonnes of iron(III) oxide. Relative atomic masses: Fe = 56, O = 16.Show worked answer →
A 4-mark Higher reacting-mass calculation worked in tonnes (the method is identical to grams).
The of (1 mark). "Moles" (1 mark, treating tonnes consistently). The ratio of to is , so amount of iron (1 mark). Mass of iron tonnes (1 mark).
Markers accept working in tonnes throughout since the ratios are unitless; the key error is using a ratio instead of .
AQA 20225 marksHydrogen reacts with nitrogen to make ammonia: . A reaction mixture contains g of nitrogen and g of hydrogen. Determine which reactant is limiting, and calculate the maximum mass of ammonia that can form. Relative atomic masses: N = 14, H = 1.Show worked answer →
A 5-mark Higher limiting-reactant question.
Moles of mol (1 mark). Moles of mol (1 mark). The equation needs mol of per mol of , so mol of needs only mol of . There is mol of available, so hydrogen is in excess and nitrogen is limiting (1 mark). Moles of mol (1 mark). of , so mass g (1 mark).
Markers reward comparing moles against the ratio, not comparing raw masses.
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Sources & how we know this
- AQA GCSE Chemistry (8462) specification — AQA (2016)