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How are the pressure, volume, temperature and amount of a gas related, and what is an ideal gas?

Kinetic theory: the gas laws, the absolute temperature scale, the equation of state pV = nRT (and pV = NkT), and the conditions under which a real gas behaves ideally.

A focused answer to the Eduqas A-Level Physics Component 1 ideal gas content, covering the experimental gas laws, the absolute temperature scale, the equation of state pV = nRT and pV = NkT, and the conditions under which a real gas behaves ideally.

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  1. What this dot point is asking
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What this dot point is asking

Eduqas wants you to state the experimental gas laws, explain the absolute temperature scale, use the ideal gas equation of state pV=nRTpV = nRT (equivalently pV=NkTpV = NkT), and state the conditions under which a real gas behaves ideally.

The answer

The gas laws

The absolute temperature scale

The equation of state

When a real gas behaves ideally

Examples in context

The ideal gas equation underpins the engineering of engines, compressors, refrigerators and pneumatic systems, and the behaviour of weather balloons and scuba tanks. Charles's law explains why a balloon expands when warmed; Boyle's law explains why a diver's lungs and bubbles expand as they rise. Meteorology and the study of planetary atmospheres rely on the gas laws to relate pressure, temperature and density.

Try this

Q1. State Boyle's law. [1 mark]

  • Cue. At constant temperature, the pressure of a fixed mass of gas is inversely proportional to its volume.

Q2. A gas of 0.50 mol0.50\ \text{mol} occupies 0.012 m30.012\ \text{m}^3 at 310 K310\ \text{K}. Find its pressure (R=8.31 J mol1 K1R = 8.31\ \text{J mol}^{-1}\ \text{K}^{-1}). [2 marks]

  • Cue. p=nRTV=0.50×8.31×3100.012=1.1×105 Pap = \frac{nRT}{V} = \frac{0.50 \times 8.31 \times 310}{0.012} = 1.1 \times 10^{5}\ \text{Pa}.

Q3. State the conditions under which a real gas behaves most like an ideal gas. [2 marks]

  • Cue. Low pressure and high temperature (low density), where the molecules are far apart and intermolecular forces are negligible.

Exam-style practice questions

Practice questions written in the style of WJEC Eduqas exam questions on this dot point, with worked answer explainers. The year tag is the paper they imitate, not the source.

Eduqas 20194 marksA sealed container of volume 2.0×103 m32.0 \times 10^{-3}\ \text{m}^3 holds gas at a pressure of 1.5×105 Pa1.5 \times 10^{5}\ \text{Pa} and a temperature of 290 K290\ \text{K}. Calculate the number of moles of gas. Take R=8.31 J mol1 K1R = 8.31\ \text{J mol}^{-1}\ \text{K}^{-1}.
Show worked answer →

Rearrange the equation of state pV=nRTpV = nRT for nn: n=pVRTn = \dfrac{pV}{RT}.

n=(1.5×105)(2.0×103)(8.31)(290)=3002410=0.124 moln = \dfrac{(1.5 \times 10^{5})(2.0 \times 10^{-3})}{(8.31)(290)} = \dfrac{300}{2410} = 0.124\ \text{mol}, about 0.12 mol0.12\ \text{mol}.

Markers reward n=pVRTn = \frac{pV}{RT}, correct substitution, and about 0.12 mol0.12\ \text{mol}.

Eduqas 20214 marksA fixed mass of ideal gas at 300 K300\ \text{K} occupies 0.025 m30.025\ \text{m}^3 at a pressure of 1.0×105 Pa1.0 \times 10^{5}\ \text{Pa}. It is heated at constant pressure until its volume is 0.030 m30.030\ \text{m}^3. Calculate the new temperature.
Show worked answer →

At constant pressure (and fixed amount of gas), VT\dfrac{V}{T} is constant, so V1T1=V2T2\dfrac{V_1}{T_1} = \dfrac{V_2}{T_2}.

Rearrange for T2T_2: T2=T1V2V1=300×0.0300.025=300×1.2=360 KT_2 = T_1 \dfrac{V_2}{V_1} = 300 \times \dfrac{0.030}{0.025} = 300 \times 1.2 = 360\ \text{K}.

Markers reward using VT\frac{V}{T} constant at constant pressure, the rearrangement, and the new temperature 360 K360\ \text{K}.

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