Why is the voltage across a battery's terminals less than its rated value when it supplies current?
Electromotive force as energy per unit charge, internal resistance, the equations linking EMF, terminal potential difference and lost volts, and measuring EMF and internal resistance experimentally.
A focused answer to AQA A-Level Physics 3.5.1.6, covering electromotive force as energy transferred per unit charge, internal resistance, the equations linking EMF, terminal potential difference and lost volts, and the experiment to measure EMF and internal resistance.
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What this dot point is asking
AQA specification point 3.5.1.6 wants you to define EMF, explain internal resistance and lost volts, use the equations linking EMF, terminal potential difference and internal resistance, and describe how to measure EMF and internal resistance from a graph.
Electromotive force
The EMF is the maximum potential difference a source can deliver, which occurs only when no current is drawn. The energy comes from chemical reactions in a cell, from electromagnetic induction in a dynamo, or from incident light in a photovoltaic cell.
Internal resistance and lost volts
Every real source has some resistance to current within itself, the internal resistance , due to the resistance of its electrolyte, electrodes or windings. When a current flows, energy is dissipated inside the source as heat.
A source with a low internal resistance (such as a car battery) can deliver large currents with little drop in terminal voltage, whereas a high internal resistance limits the maximum useful current.
Measuring EMF and internal resistance
The EMF alone can be estimated directly as the terminal pd measured by a high-resistance voltmeter when negligible current flows.
Try this
Q1. Define the EMF of a cell. [1 mark]
- Cue. The energy transferred to each coulomb of charge passing through the source.
Q2. A cell of EMF has a terminal pd of when supplying . Calculate the internal resistance. [2 marks]
- Cue. Lost volts ; .
Q3. State the terminal pd of a cell when no current is drawn from it. [1 mark]
- Cue. It equals the EMF.
Exam-style practice questions
Practice questions written in the style of AQA exam questions on this dot point, with worked answer explainers. The year tag is the paper they imitate, not the source.
AQA 20184 marksA cell of EMF and internal resistance is connected to a resistor. Calculate the current in the circuit and the terminal potential difference across the cell.Show worked answer →
Use the EMF equation to find the current, including the internal resistance in the total.
.
Terminal pd is the voltage across the external resistor, . Equivalently .
Markers reward including the internal resistance in the total resistance and recognising that the terminal pd is less than the EMF because of the lost volts.
AQA 20225 marksA student measures the terminal potential difference of a cell for several values of current and plots terminal pd against current, obtaining a straight line. Explain how the EMF and internal resistance can be found from this graph, and state what the line shows about the cell.Show worked answer →
The cell obeys , which has the form with on the y-axis and on the x-axis. The y-intercept (where ) gives the EMF , because with no current there are no lost volts.
The gradient is , so the internal resistance is the magnitude of the gradient. A straight line confirms that is constant over the range tested.
The line slopes downwards: as the current rises, the lost volts grow, so the terminal pd falls below the EMF.
Markers reward identifying the y-intercept as the EMF, the gradient magnitude as the internal resistance, and explaining the negative slope through lost volts.
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Sources & how we know this
- AQA A-level Physics (7408) specification — AQA (2017)